Selvanayagam S, Ravikumar K, Saravanan P, Raghunathan R
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o751. doi: 10.1107/S1600536811007124. Epub 2011 Mar 2.
In the title compound, C(32)H(28)N(2)O(2), the pyrrolidine ring adopts an envelope conformation, whereas the cyclo-hexa-none ring in the tetra-hydro-naphthalene fused-ring system adopts a half-chair conformation. The oxindole ring system is oriented at an angle of 48.2 (1)° with respect to the naphthyl ring system. An intra-molecular C-H⋯O close contact is observed. In the crystal, mol-ecules associate via two C-H⋯O hydrogen bonds, forming R(2) (2)(14) and R(2) (2)(10) dimers.
在标题化合物C(32)H(28)N(2)O(2)中,吡咯烷环呈信封式构象,而四氢萘稠环体系中的环己酮环呈半椅式构象。吲哚酮环系相对于萘基环系的取向角度为48.2 (1)°。观察到分子内存在C—H⋯O紧密接触。在晶体中,分子通过两个C—H⋯O氢键缔合,形成R(2) (2)(14)和R(2) (2)(10)二聚体。