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N,N'-双[(4-甲基苯基)磺酰基]己二酰胺

N,N'-Bis[(4-methyl-phen-yl)sulfon-yl]adipamide.

作者信息

Rodrigues Vinola Z, Foro Sabine, Gowda B Thimme

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o788. doi: 10.1107/S1600536811007756. Epub 2011 Mar 5.

DOI:10.1107/S1600536811007756
PMID:21754079
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099843/
Abstract

In the centrosymmetric title compound, C(20)H(24)N(2)O(6)S(2), the N-H and C=O bonds are trans to each other. In the crystal, inter-molecular N-H⋯O(S) hydrogen bonds link the mol-ecules into zigzag chains running along the b axis. The O atom involved in the hydrogen bond has a longer S-O bond than the other O atom bonded to S [1.441 (2) versus 1.428 (2) Å].

摘要

在中心对称的标题化合物C₂₀H₂₄N₂O₆S₂中,N-H键和C=O键彼此呈反式。在晶体中,分子间的N-H⋯O(S)氢键将分子连接成沿b轴延伸的锯齿链。参与氢键的O原子的S-O键长比与S键合的另一个O原子的S-O键长更长[1.441 (2) Å对1.428 (2) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e2/3099843/650148b04ba9/e-67-0o788-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e2/3099843/ac02e1ea7f9a/e-67-0o788-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e2/3099843/650148b04ba9/e-67-0o788-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e2/3099843/ac02e1ea7f9a/e-67-0o788-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22e2/3099843/650148b04ba9/e-67-0o788-fig2.jpg

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本文引用的文献

1
N,N'-Bis[(2-methyl-phenyl)sulfon-yl]adipamide.N,N'-双[(2-甲基苯基)磺酰基]己二酰胺
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o789. doi: 10.1107/S1600536811007203. Epub 2011 Mar 5.
2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.