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2,4,6-三硝基-N-[4-(苯基重氮基)苯基]苯胺

2,4,6-Trinitro-N-[4-(phenyl-diazen-yl)phen-yl]aniline.

作者信息

Smith Graham, Wermuth Urs D

机构信息

Faculty of Science and Technology, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o948. doi: 10.1107/S160053681101004X. Epub 2011 Mar 23.

Abstract

The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl-diazen-yl)aniline (aniline yellow) with picryl-sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl-diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate-aniline ring system is 48.76 (12)°. The mol-ecule contains an intra-molecular aniline-nitro N-H⋯O hydrogen bond.

摘要

标题化合物C(18)H(12)N(6)O(6)由4-(苯基重氮基)苯胺(苯胺黄)与苦味磺酸反应制备而成。二苯基重氮基环系统的两个苯环形成的二面角为6.55 (13)°,苦味酸盐-苯胺环系统的环形成的二面角为48.76 (12)°。该分子包含一个分子内苯胺-硝基N-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/decc/3099790/b947044f0e1b/e-67-0o948-fig1.jpg

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