• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2,4,6-三硝基-N-[4-(苯基重氮基)苯基]苯胺

2,4,6-Trinitro-N-[4-(phenyl-diazen-yl)phen-yl]aniline.

作者信息

Smith Graham, Wermuth Urs D

机构信息

Faculty of Science and Technology, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o948. doi: 10.1107/S160053681101004X. Epub 2011 Mar 23.

DOI:10.1107/S160053681101004X
PMID:21754214
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099790/
Abstract

The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl-diazen-yl)aniline (aniline yellow) with picryl-sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl-diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate-aniline ring system is 48.76 (12)°. The mol-ecule contains an intra-molecular aniline-nitro N-H⋯O hydrogen bond.

摘要

标题化合物C(18)H(12)N(6)O(6)由4-(苯基重氮基)苯胺（苯胺黄）与苦味磺酸反应制备而成。二苯基重氮基环系统的两个苯环形成的二面角为6.55 (13)°，苦味酸盐-苯胺环系统的环形成的二面角为48.76 (12)°。该分子包含一个分子内苯胺-硝基N-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/decc/3099790/b947044f0e1b/e-67-0o948-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/decc/3099790/b947044f0e1b/e-67-0o948-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/decc/3099790/b947044f0e1b/e-67-0o948-fig1.jpg

相似文献

1
2,4,6-Trinitro-N-[4-(phenyl-diazen-yl)phen-yl]aniline.2,4,6-三硝基-N-[4-(苯基重氮基)苯基]苯胺
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o948. doi: 10.1107/S160053681101004X. Epub 2011 Mar 23.
2
2-(4-Amino-phen-yl)-1-phenyl-diazenium 2,4,6-trinitro-phenolate.2-（4-氨基苯基）-1-苯基重氮鎓2,4,6-三硝基苯酚盐
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o878. doi: 10.1107/S1600536811008968. Epub 2011 Mar 12.
3
4-(4-Amino-phenyl-sulfon-yl)aniline-1,3,5-trinitro-benzene (1/2).4-（4-氨基-苯磺酰基）苯胺-1,3,5-三硝基苯（1/2）
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o494. doi: 10.1107/S1600536812001742. Epub 2012 Jan 21.
4
1-[(Bromo-meth-yl)(phen-yl)meth-ylene]-2-(2,4-dinitro-phen-yl)hydrazine.1-[(溴甲基)(苯基)亚甲基]-2-(2,4-二硝基苯基)肼
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):o1221-2. doi: 10.1107/S1600536809016225.
5
Orphenadrinium picrate picric acid.苦味酸奥芬那君苦味酸。
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 24;66(Pt 3):o682-3. doi: 10.1107/S1600536810006379.
6
2,2'-({4-[(4-Nitro-phen-yl)diazen-yl]phen-yl}imino)-diethanol.2,2'-({4-[(4-硝基苯基)重氮基]苯基}亚氨基)二乙醇
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):o22. doi: 10.1107/S1600536812049239. Epub 2012 Dec 5.
7
(R,R)-1-Acetyl-1'-(2,4,6-trinitro-phen-yl)-2,2'-bipyrrolidine.（R，R）-1-乙酰基-1'-（2,4,6-三硝基苯基）-2,2'-联吡咯烷
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):o144-5. doi: 10.1107/S1600536812051161. Epub 2012 Dec 22.
8
2,2-Diphenyl-N-(2,4,5-trichloro-phen-yl)acetamide.2,2-二苯基-N-(2,4,5-三氯苯基)乙酰胺
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2659-60. doi: 10.1107/S160053681203440X. Epub 2012 Aug 8.
9
(E)-4-[(4-Nitro-phen-yl)diazen-yl]phenyl anthracene-9-carboxyl-ate.
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):o2258. doi: 10.1107/S1600536808034958.
10
N-{2-[(4S)-4-tert-Butyl-4,5-dihydro-1,3-oxazol-2-yl]phen-yl}-5,6-diphenyl-1,2,4-triazin-3-amine.N-{2-[(4S)-4-叔丁基-4,5-二氢-1,3-恶唑-2-基]苯基}-5,6-二苯基-1,2,4-三嗪-3-胺
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o651. doi: 10.1107/S1600536811005411.

引用本文的文献

1
Theoretical and Experimental Studies of N,N-Dimethyl-N'-Picryl-4,4'-Stilbenediamine.N，N-二甲基-N'-苦味基-4，4'-二苯乙烯二胺的理论与实验研究
J Fluoresc. 2018 Jan;28(1):13-19. doi: 10.1007/s10895-014-1425-9. Epub 2014 Aug 9.

本文引用的文献

1
2-(4-Amino-phen-yl)-1-phenyl-diazenium 2,4,6-trinitro-phenolate.2-（4-氨基苯基）-1-苯基重氮鎓2,4,6-三硝基苯酚盐
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o878. doi: 10.1107/S1600536811008968. Epub 2011 Mar 12.
2
Proton transfer versus nontransfer in compounds of the diazo-dye precursor 4-(phenyldiazenyl)aniline (aniline yellow) with strong organic acids: the 5-sulfosalicylate and the dichroic benzenesulfonate salts, and the 1:2 adduct with 3,5-dinitrobenzoic acid.重氮染料前体4-（苯基重氮基）苯胺（苯胺黄）与强有机酸形成的化合物中的质子转移与非转移：5-磺基水杨酸盐和二色性苯磺酸盐，以及与3,5-二硝基苯甲酸形成的1:2加合物。
Acta Crystallogr C. 2009 Oct;65(Pt 10):o543-8. doi: 10.1107/S0108270109036622. Epub 2009 Sep 30.
3
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
5
Pseudopolymorphism in brucine: brucine-water (1/2), the third crystal hydrate of brucine.马钱子碱中的假多晶型现象：马钱子碱 - 水合物（1/2），马钱子碱的第三种结晶水合物。
Acta Crystallogr C. 2007 Aug;63(Pt 8):o489-92. doi: 10.1107/S0108270107032295. Epub 2007 Jul 26.