Danish Muhammad, Ghafoor Sabiha, Ahmad Nazir, Starosta Wojciech, Leciejewicz Janusz
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m519. doi: 10.1107/S1600536811011184. Epub 2011 Apr 7.
In the title complex, [Sn(C(6)H(5))(3)(C(8)H(5)N(2)O(6))(CH(3)OH)], the Sn(IV) ion is coordinated in a slightly distorted trigonal-bipyramidal geometry by three phenyl ligands in the equatorial plane and by a 2-methyl-3,5-dinitro-benzene-carboxyl-ato ligand and a methanol ligand at the apical sites. In the crystal, complex mol-ecules are linked via inter-molecular O-H⋯O hydrogen bonds, forming chains along [100].
在标题配合物[Sn(C₆H₅)₃(C₈H₅N₂O₆)(CH₃OH)]中，Sn(IV)离子通过赤道平面上的三个苯基配体以及顶端位置的一个2-甲基-3,5-二硝基苯甲酸根配体和一个甲醇配体，以略微扭曲的三角双锥几何构型配位。在晶体中，配合物分子通过分子间O—H⋯O氢键相连，沿[100]方向形成链状结构。
