• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

四水合硝酸双（μ-2-氧化苯甲酸根）二-μ(3)-羟基双（2,2'-联吡啶）四铜（II）

Tetra-kis(2,2'-bipyrid-ine)di-μ(3)-hydroxido-bis(μ-2-oxidobenzoato)tetra-copper(II) dinitrate tetra-hydrate.

作者信息

Feng Miao, Gu Chao, Mi Huai-Feng, Hu Tong-Liang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m520. doi: 10.1107/S1600536811011433. Epub 2011 Apr 7.

DOI:10.1107/S1600536811011433
PMID:21754263
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3089088/
Abstract

The tetra-nuclear title complex, Cu(4)(C(7)H(4)O(3))(2)(OH)(2)(C(10)H(8)N(2))(4)(2)·4H(2)O, has a crystallographically imposed centre of symmetry. The Cu(II) atoms display a distorted square-pyramidal coordination geometry and are linked by two μ(2)-phenolate O atoms from the salicylate ligands and two μ(3)-hydroxo groups, forming a Cu(4)O(4) core that adopts a 'stepped-cubane' geometry. In the crystal, the cations are linked by O-H⋯O hydrogen bonds to the nitrate anions, which are in turn connected via O-H⋯O inter-actions to centrosymmentric water tetra-mers.

摘要

四核标题配合物Cu(4)(C(7)H(4)O(3))(2)(OH)(2)(C(10)H(8)N(2))(4)(2)·4H(2)O具有晶体学上的对称中心。铜(II)原子呈现出扭曲的四方锥配位几何构型，并通过来自水杨酸酯配体的两个μ(2)-酚氧原子和两个μ(3)-羟基相连，形成一个采用“阶梯式立方烷”几何构型的Cu(4)O(4)核。在晶体中，阳离子通过O-H⋯O氢键与硝酸根阴离子相连，而硝酸根阴离子又通过O-H⋯O相互作用与中心对称的水四聚体相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eba8/3089088/859b51368cd9/e-67-0m520-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eba8/3089088/db5f178ac552/e-67-0m520-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eba8/3089088/859b51368cd9/e-67-0m520-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eba8/3089088/db5f178ac552/e-67-0m520-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eba8/3089088/859b51368cd9/e-67-0m520-fig2.jpg

相似文献

1
Tetra-kis(2,2'-bipyrid-ine)di-μ(3)-hydroxido-bis(μ-2-oxidobenzoato)tetra-copper(II) dinitrate tetra-hydrate.四水合硝酸双（μ-2-氧化苯甲酸根）二-μ(3)-羟基双（2,2'-联吡啶）四铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m520. doi: 10.1107/S1600536811011433. Epub 2011 Apr 7.
2
Tetra-kis(2,2'-bipyrid-yl)dichlorido-di-μ(3)-hydroxido-di-μ(2)-hydroxido-tetra-copper(II) dinitrate hexa-hydrate.四硝酸根合二水合四（2,2'-联吡啶基）二氯二μ(3)-羟基二μ(2)-羟基四铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m131-2. doi: 10.1107/S160053680804381X.
3
Crystal structures of bis- and hexakis[(6,6'-di-hydroxy-bipyridine)copper(II)] nitrate coordination complexes.硝酸双-和六-[(6,6'-二羟基联吡啶)铜(II)]配位络合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 4;71(Pt 12):1447-53. doi: 10.1107/S205698901502037X. eCollection 2015 Dec 1.
4
Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate.二-μ(4)-琥珀酸根四-双[水合菲咯啉铜(II)]四硝酸酯四水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1284. doi: 10.1107/S1600536809039580.
5
Tetra-μ(3)-iodido-tetra-kis-{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN(3)]copper(I)}.四-μ(3)-碘代-四-基-{[乙基 2-(1H-苯并咪唑-1-基)乙酸根-κN(3)]铜(I)}
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m796. doi: 10.1107/S160053681202257X. Epub 2012 May 26.
6
Hexanuclear copper(II) complex of 2-hy-droxy-,'-bis-[1-(2-hy-droxy-phen-yl)ethyl-idene]propane-1,3-di-amine incorporating an open-cubane core.含有开放立方烷核心的2-羟基-，'-双-[1-(2-羟基苯基)亚乙基]丙烷-1,3-二胺的六核铜(II)配合物。
Acta Crystallogr E Crystallogr Commun. 2021 Jun 11;77(Pt 7):708-713. doi: 10.1107/S2056989021005570. eCollection 2021 Jul 1.
7
Di-μ-hydroxido-bis-[hemiaqua-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-copper(II)] bis-(tetra-fluoridoborate).二-μ-羟基-双-[半水合-(N,N,N',N'-四甲基乙烷-1,2-二胺)-铜(II)] 双-(四氟硼酸)盐
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m784. doi: 10.1107/S1600536812021836. Epub 2012 May 19.
8
Tetra-kis[μ-1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene-κN:N']tetra-kis-(μ-methano-lato-κO:O)bis-(μ-perchlorato-κO:O')tetra-copper(II) bis-(perchlorate).四-双[μ-1,4-双-(4,5-二氢-1,3-恶唑-2-基)苯-κN:N']四-双-(μ-亚甲基-κO:O)双-(μ-高氯酸根-κO:O')四铜(II)双-(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1080-1. doi: 10.1107/S160053681102705X. Epub 2011 Jul 13.
9
Tetra-kis(μ(3)-2-{[1,1-bis-(hydroxy-meth-yl)-2-oxidoeth-yl]imino-meth-yl}-6-methoxy-phenol-ato)tetra-nickel(II) tetra-hydrate.四水合四 - 双（μ(3)-2-{[1,1 - 二（羟甲基）-2 - 氧化乙 - 基]亚氨基甲基}-6 - 甲氧基苯酚根合）四镍（II）
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 16;64(Pt 5):m675-6. doi: 10.1107/S1600536808009872.
10
Tetra-kis(1,10-phenanthroline)bis-(μ-pyridine-2,6-dicarboxyl-ato)(pyridine-2,6-di-carboxyl-ato)dicopper(II)terbium(III) nitrate tetra-hydrate.四（1,10-菲咯啉）双（μ-吡啶-2,6-二羧酸根）（吡啶-2,6-二羧酸根）二铜（II）铽（III）硝酸四水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1084-5. doi: 10.1107/S1600536812031686. Epub 2012 Jul 18.

本文引用的文献

1
Tetra-kis(2,2'-bipyrid-yl)dichlorido-di-μ(3)-hydroxido-di-μ(2)-hydroxido-tetra-copper(II) dinitrate hexa-hydrate.四硝酸根合二水合四（2,2'-联吡啶基）二氯二μ(3)-羟基二μ(2)-羟基四铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m131-2. doi: 10.1107/S160053680804381X.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Formation of a tetranuclear copper (II) cluster assembled by metal-assisted hydrolysis and desulfurization of bis(3,5-dimethylpyrazolyl)methylphosphine sulfide, MeP(S)(3,5-Me2Pz)2.
通过双（3,5-二甲基吡唑基）甲基膦硫化物MeP(S)(3,5-Me2Pz)2的金属辅助水解和脱硫组装形成四核铜（II）簇。
Inorg Chem. 2000 Jul 24;39(15):3238-42. doi: 10.1021/ic991255k.