Wu Gui-Ling, Ou Chun-Ping, Wang Feng, Zhang Jian-Ming, Lan She-Min
Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m531. doi: 10.1107/S1600536811011810. Epub 2011 Apr 7.
In the title compound, Fe(C(38)H(38)N(10))(2)·CH(3)OH, the Fe(II) atom has a distorted octa-hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N',N'-tetra-kis-(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol mol-ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N-H⋯O and C-H⋯O hydrogen bonds, as well as π-π stacking inter-actions between the imidazol rings and between the imidazol and benzene rings [centroid-centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network.
在标题化合物Fe(C₃₈H₃₈N₁₀)₂·CH₃OH中，Fe(II)原子具有扭曲的八面体配位环境，由一个N,N,N',N'-四(苯并咪唑-2-基甲基)环己烷-1,2-反式二胺配体的四个苯并咪唑N原子和两个氨基N原子配位。未配位的溶剂甲醇分子通过氢键与高氯酸根阴离子的一个O原子相连。其中一个高氯酸根阴离子在两组位置上无序分布，占有率分别为0.539 (14)和0.461 (14)。N-H⋯O和C-H⋯O氢键以及咪唑环之间和咪唑环与苯环之间的π-π堆积相互作用[质心-质心距离 = 3.714 (2)和3.705 (2) Å]形成了三维网络。
