反式双（2-乙酰氨基-5-甲基苯甲酸根-κO）四水合锌
trans-Bis(2-acet-amido-5-methyl-benzoato-κO)tetra-aqua-zinc.
作者信息
Huang Jin-Feng, Zheng Jian-You, Dai Yu-Mei
机构信息
College of Chemistry & Material Science, Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m542. doi: 10.1107/S1600536811012013. Epub 2011 Apr 7.
In the title compound, [Zn(C(10)H(10)NO(3))(2)(H(2)O)(4)], the Zn(II) atom lies on a crystallographic inversion center and is six-coordinated by two monodentate trans-related 2-(N-acetyl-amino)-5-methyl-benzoato ligands and four water mol-ecules, giving a slightly distorted octa-hedral geometry. There are two intra-molecular hydrogen bonds [amine N-H⋯O(carbox-yl) and water O-H⋯O(carbox-yl)], while extensive inter-molecular water O-H⋯O hydrogen-bonding inter-actions extend the complex units into a two-dimensional network structure along (100).
在标题化合物[Zn(C₁₀H₁₀NO₃)₂(H₂O)₄]中，Zn(II)原子位于一个晶体学反演中心，由两个单齿的反式相关2-(N-乙酰基-氨基)-5-甲基苯甲酸酯配体和四个水分子进行六配位，形成略微扭曲的八面体几何构型。存在两个分子内氢键[胺N-H⋯O(羧基)和水O-H⋯O(羧基)]，同时广泛的分子间水O-H⋯O氢键相互作用将配合物单元沿(100)扩展成二维网络结构。
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