三水合丙烷 -1,2 - 二铵三（吡啶 -2,6 - 二羧酸根 -κO,N,O）锆（IV）
Propane-1,2-diaminium tris-(pyridine-2,6-dicarboxyl-ato-κO,N,O)zirconate(IV) trihydrate.
作者信息
Pasdar Hoda, Shakiba Shahrzad, Aghabozorg Hossein, Notash Behrouz
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m587. doi: 10.1107/S1600536811008488. Epub 2011 Apr 13.
Abstract
In the title compound, (C(3)H(12)N(2))[Zr(C(7)H(3)NO(4))(3)]·3H(2)O, the Zr(IV) cation is chelated by three pyridine-2,6-dicarboxyl-ate anions in a distorted tricapped trigonal-prismatic environment. The crystal structure is stabilized by inter-molecular N-H⋯O and O-H⋯O hydrogen bonds.
摘要
在标题化合物（C₃H₁₂N₂）[Zr（C₇H₃NO₄）₃]·3H₂O中，Zr（IV）阳离子在扭曲的三帽三棱柱环境中被三个吡啶-2,6-二羧酸根阴离子螯合。晶体结构通过分子间的N-H⋯O和O-H⋯O氢键得以稳定。
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