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苯-1,3-二铵双（吡啶-2,6-二羧酸根）镍（II）五水合物

Benzene-1,3-diammonium bis-(pyridine-2,6-dicarboxyl-ato)nickelate(II) penta-hydrate.

作者信息

Pasdar Hoda, Sadat Kashani Saghi, Aghabozorg Hossein, Notash Behrouz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):m193-4. doi: 10.1107/S1600536810054371.

DOI:10.1107/S1600536810054371
PMID:21522862
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3051631/
Abstract

In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral fashion. The crystal packing is stabilized by inter-molecular O-H⋯O and N-H⋯O and weak C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distances = 3.4669 (19) and 3.764 (2) Å].

摘要

在标题化合物（C₆H₁₀N₂）[Ni（C₇H₃NO₄）₂]·5H₂O中，Ni（II）离子由来自两个吡啶-2,6-二羧酸酯配体的两个N原子和四个O原子以扭曲的八面体构型进行六配位。晶体堆积通过分子间的O—H⋯O、N—H⋯O以及弱的C—H⋯O氢键和π-π相互作用[质心-质心距离 = 3.4669（19）和3.764（2）Å]得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aee8/3051631/685ccc7b443d/e-67-0m193-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aee8/3051631/e38e86fac84b/e-67-0m193-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aee8/3051631/cadab4dcfeb8/e-67-0m193-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aee8/3051631/685ccc7b443d/e-67-0m193-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aee8/3051631/e38e86fac84b/e-67-0m193-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aee8/3051631/cadab4dcfeb8/e-67-0m193-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aee8/3051631/685ccc7b443d/e-67-0m193-fig3.jpg

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