Suppr超能文献

(2-Hy-droxy-acetato-κO)bis-(1,10-phenan-throline-κN,N')copper(II) nitrate.

作者信息

Kong Ya-Jie, Yuan Zhuang-Dong

机构信息

Department of Chemistry and Chemical Engineering, Jining University, Qufu 273155, Shandong, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m592. doi: 10.1107/S1600536811013110. Epub 2011 Apr 13.

Abstract

In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hy-droxy-acetate anion in a distorted square-pyramidal geometry. The hy-droxy group of the hy-droxy-acetate ligand links with the counter NO(3) (-) anion via a pair of bifurcated O-H⋯O hydrogen bonds. The centroid-centroid distance of 3.5676 (14) Å between benzene rings of parallel phen ligands of adjacent mol-ecules suggests the existence of π-π stacking. Weak inter-molecular C-H⋯O hydrogen bonding is also present in the crystal structure.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35a9/3089357/f679b2cbca9d/e-67-0m592-fig1.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验