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(2-Hy-droxy-acetato-κO)bis-(1,10-phenan-throline-κN,N')copper(II) nitrate.

作者信息

Kong Ya-Jie, Yuan Zhuang-Dong

机构信息

Department of Chemistry and Chemical Engineering, Jining University, Qufu 273155, Shandong, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m592. doi: 10.1107/S1600536811013110. Epub 2011 Apr 13.

DOI:10.1107/S1600536811013110
PMID:21754313
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3089357/
Abstract

In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hy-droxy-acetate anion in a distorted square-pyramidal geometry. The hy-droxy group of the hy-droxy-acetate ligand links with the counter NO(3) (-) anion via a pair of bifurcated O-H⋯O hydrogen bonds. The centroid-centroid distance of 3.5676 (14) Å between benzene rings of parallel phen ligands of adjacent mol-ecules suggests the existence of π-π stacking. Weak inter-molecular C-H⋯O hydrogen bonding is also present in the crystal structure.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35a9/3089357/b57cfc8d0865/e-67-0m592-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35a9/3089357/f679b2cbca9d/e-67-0m592-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35a9/3089357/b57cfc8d0865/e-67-0m592-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35a9/3089357/f679b2cbca9d/e-67-0m592-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/35a9/3089357/b57cfc8d0865/e-67-0m592-fig2.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
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