Betz Richard, McCleland Cedric, Marchand Harold
Nelson Mandela Metropolitan University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth 6031, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1195. doi: 10.1107/S1600536811014553. Epub 2011 Apr 22.
The title compound, C(13)H(13)N, is an N-alkyl-ated derivative of aniline. The N atom is present in a nearly planar mol-ecular geometry (angles sums at the N atom are 358 and 359° in the two molecules of the asymmetric unit). The planes defined by the aromatic rings intersect at angles of 80.76 (4) and 81.40 (4)° in the two molecules. In the crystal, N-H⋯Cg inter-actions connect the two mol-ecules of the asymmetric unit to form infinite homodromic chains along the crystallographic b axis [N⋯π = 3.4782 (12) and 3.4642 (13) Å].
标题化合物C₁₃H₁₃N是苯胺的N-烷基化衍生物。N原子处于近乎平面的分子几何构型中（不对称单元的两个分子中N原子处的角度总和分别为358°和359°）。两个分子中由芳环定义的平面以80.76(4)°和81.40(4)°的角度相交。在晶体中，N-H⋯Cg相互作用将不对称单元的两个分子连接起来，沿着结晶学b轴形成无限的同向链[N⋯π = 3.4782(12)和3.4642(13) Å]。
