Muthukumaran J, Parthiban A, Manivel P, Rao H Surya Prakash, Krishna R
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1276-7. doi: 10.1107/S1600536811015595. Epub 2011 Apr 29.
In the title compound, C(12)H(13)N(3)O(6), the dihydro-pyran ring adopts a near screw-boat conformation. The dihedral angle between the mean planes of the benzene and dihydro-pyran rings is 6.35 (5)°. An intra-molecular N-H⋯O hydrogen bond generates an S(6) motif, which stabilizes the mol-ecular conformation. In the crystal, weak inter-molecular C-H⋯O, N-H⋯O and C-H⋯π hydrogen bonds contribute to the stabilization of the packing.
在标题化合物C(12)H(13)N(3)O(6)中,二氢吡喃环呈近似船式构象。苯环和二氢吡喃环平均平面之间的二面角为6.35 (5)°。分子内N—H⋯O氢键形成一个S(6)环系,稳定了分子构象。在晶体中,弱的分子间C—H⋯O、N—H⋯O和C—H⋯π氢键有助于堆积结构的稳定。