四-μ-乙酸根-κO:O'-双-[(2-氨基-3,5-二氯吡啶-κN)铜(II)](铜-铜)
Tetra-μ-acetato-κO:O'-bis-[(2-amino-3,5-dichloro-pyridine-κN)copper(II)](Cu-Cu).
作者信息
Chang Hui-Chang, Cole Jacqueline M, Lin Tze-Chia, Waddell Paul G
机构信息
Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE, England.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m691. doi: 10.1107/S1600536811015662. Epub 2011 May 7.
Abstract
The title binuclear Cu(II) complex, [Cu(2)(CH(3)CO(2))(4)(C(5)H(4)Cl(2)N(2))(2)], is disposed about a crystallographic inversion center, located at the mid-point of the Cu-Cu connecting line. The Cu⋯Cu distance is 2.6600 (6) Å and each metal atom exhibits a Jahn-Teller-distorted octa-hedral geometry.
摘要
双核铜（II）配合物[Cu₂(CH₃CO₂)₄(C₅H₄Cl₂N₂)₂]围绕一个位于铜-铜连接线中点的晶体学反演中心排列。铜⋯铜间距为2.6600 (6) Å，每个金属原子呈现出姜-泰勒畸变的八面体几何构型。
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