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二水合 -(2,2'-联吡啶 -6,6'-二羧酸根)镍(II)

Diaqua-(2,2'-bipyridine-6,6'-dicarboxyl-ato)nickel(II).

作者信息

Hu Shui, Wen Shipeng, Hu Huai-Ming, Liu Li

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m718. doi: 10.1107/S1600536811016400. Epub 2011 May 7.

Abstract

In the title compound, [Ni(C(12)H(6)N(2)O(4))(H(2)O)(2)], the Ni(II) atom (site symmetry 2) displays a distorted cis-NiN(2)O(4) octa-hedral coordination geometry with two N atoms and two O atoms of the tetra-dentate 2,2'-bipyridine-6,6'-dicarboxyl-ate ligand in the equatorial plane and two water mol-ecules in axial positions. The complete dianionic ligand is generated by crystallographic twofold symmetry. In the crystal, a two-dimensional supra-molecular structure parallel to (001) is formed through O-H⋯O hydrogen-bond inter-actions between the coordinated water mol-ecules and the O atoms of nearby carboxyl-ate groups.

摘要

在标题化合物[Ni(C₁₂H₆N₂O₄)(H₂O)₂]中,Ni(II)原子(位点对称性为2)呈现出扭曲的顺式-NiN₂O₄八面体配位几何构型,两个N原子和四齿2,2'-联吡啶-6,6'-二羧酸酯配体的两个O原子位于赤道平面,两个水分子位于轴向位置。完整的二价阴离子配体由晶体学二重对称性产生。在晶体中,通过配位水分子与附近羧酸根基团的O原子之间的O-H⋯O氢键相互作用,形成了平行于(001)的二维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a66d/3120548/8d53ebf6edb4/e-67-0m718-fig1.jpg

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