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Diaqua-(2,2'-bipyridine-6,6'-dicarboxyl-ato)nickel(II).

作者信息

Hu Shui, Wen Shipeng, Hu Huai-Ming, Liu Li

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m718. doi: 10.1107/S1600536811016400. Epub 2011 May 7.

Abstract

In the title compound, [Ni(C(12)H(6)N(2)O(4))(H(2)O)(2)], the Ni(II) atom (site symmetry 2) displays a distorted cis-NiN(2)O(4) octa-hedral coordination geometry with two N atoms and two O atoms of the tetra-dentate 2,2'-bipyridine-6,6'-dicarboxyl-ate ligand in the equatorial plane and two water mol-ecules in axial positions. The complete dianionic ligand is generated by crystallographic twofold symmetry. In the crystal, a two-dimensional supra-molecular structure parallel to (001) is formed through O-H⋯O hydrogen-bond inter-actions between the coordinated water mol-ecules and the O atoms of nearby carboxyl-ate groups.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a66d/3120548/8d53ebf6edb4/e-67-0m718-fig1.jpg

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