Yamin Bohari M, Osman Uwaisulqarni M
School of Chemical Sciences and Food Technology, Universiti Kebangsaan Malaysia, UKM 43500 Bangi Selangor, Malaysia.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1286. doi: 10.1107/S1600536811014954. Epub 2011 May 7.
In the title compound, C(22)H(17)ClN(4)O(2)S(2), both benzoyl groups are trans to the thiono group across their C-N bonds. The two methyl-ene carbamothioyl formamide fragments of the benzoyl-thio-urea side arms make a dihedral angle of 87.00 (10)°. The mol-ecule is stabilized by intra-molecular N-H⋯O, N-H⋯S and C-H⋯·S hydrogen bonds. In the crystal, mol-ecules are linked by N-H⋯O and N-H⋯S inter-molecular hydrogen bonds into zigzag chains along the a axis.
在标题化合物C₂₂H₁₇ClN₄O₂S₂中，两个苯甲酰基在其C-N键上均与硫羰基呈反式。苯甲酰硫脲侧臂的两个亚甲基氨基甲硫酰甲酰胺片段形成的二面角为87.00 (10)°。分子通过分子内N-H⋯O、N-H⋯S和C-H⋯S氢键得以稳定。在晶体中，分子通过N-H⋯O和N-H⋯S分子间氢键沿a轴连接成锯齿链。
