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N-叔丁基-3-均三甲苯基丙酰胺

N-tert-Butyl-3-mesitylpropanamide.

作者信息

Maharramov Abel M, Khalilov Ali N, Gurbanov Atash V, Brito Iván

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1307. doi: 10.1107/S1600536811015856. Epub 2011 May 7.

DOI:10.1107/S1600536811015856
PMID:21754709
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120507/
Abstract

In the title compound, C(16)H(25)NO, the N-tert-butyl-propanamide fragment is essentially planar, with the exception of two C atoms of the tert-butyl group (r.m.s. deviation = 0.005 Å), forming a dihedral angle of 84.09 (10)° with the plane of the mesityl fragment (r.m.s. deviation = 0.002 Å). The crystal packing is stabilized by an inter-molecular N-H⋯O hydrogen bond, which links the mol-ecules into chains with graph-set notation C(4) running parallel to the c axis.

摘要

在标题化合物C₁₆H₂₅NO中,N-叔丁基丙酰胺片段基本呈平面状,叔丁基的两个碳原子除外(均方根偏差 = 0.005 Å),与均三甲苯基片段的平面形成84.09(10)°的二面角(均方根偏差 = 0.002 Å)。晶体堆积通过分子间N-H⋯O氢键得以稳定,该氢键将分子连接成链,其图形集符号为C(4),平行于c轴延伸。