1-苄基-3,5-双-(4-甲基-亚苄基)-4-氧代哌啶-1-鎓氯化物乙酸单溶剂合物
1-Benzyl-3,5-bis-(4-methyl-benzyl-idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate.
作者信息
Sun Ju-Feng, Xing Juan, Han Jing-Tian
机构信息
Binzhou Medical College, Yantai 264003, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1350. doi: 10.1107/S1600536811016138. Epub 2011 May 7.
In the title solvated mol-ecular salt, C(28)H(28)NO(+)·Cl(-)·C(2)H(4)O(2), the central piperidinium ring of the cation adopts an envelope conformation with the N atom displaced by 0.798 (2) Å from the mean plane of the five C atoms. In the crystal, the components are linked by N-H⋯Cl and O-H⋯Cl hydrogen bonds into trimeric assemblies. C-H⋯Cl and C-H⋯π inter-actions further consolidate the packing.
在标题溶剂化分子盐C(28)H(28)NO(+)·Cl(-)·C(2)H(4)O(2)中，阳离子的中心哌啶环呈信封构象，N原子偏离五个C原子平均平面0.798(2)Å。在晶体中，各组分通过N-H⋯Cl和O-H⋯Cl氢键连接成三聚体聚集体。C-H⋯Cl和C-H⋯π相互作用进一步巩固了堆积。
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