Khan Mohd Shaheen, Sulaiman Othman, Hashim Rokiah, Hemamalini Madhukar, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1368. doi: 10.1107/S1600536811016783. Epub 2011 May 11.
The asymmetric unit of the title compound, C(27)H(46), contains two crytallographically independent cholest-5-ene mol-ecules (A and B). In each mol-ecule, the three six-membered rings are all in chair conformations, while the five-membered ring is in a twist conformation. The terminal isopropyl group of mol-ecule A has a (-)-gauche conformation, whereas that of mol-ecule B has a (+)-gauche conformation. No significant inter-molecular inter-actions are observed in the crystal structure.
标题化合物C(27)H(46)的不对称单元包含两个晶体学独立的胆甾-5-烯分子(A和B)。在每个分子中,三个六元环均呈椅式构象,而五元环呈扭曲构象。分子A的末端异丙基具有(-)-gauche构象,而分子B的末端异丙基具有(+)-gauche构象。在晶体结构中未观察到明显的分子间相互作用。