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（S）-苄基 3-（4-羟基苯基）-2-（三苯甲基氨基）丙酸酯

(S)-Benzyl 3-(4-hy-droxy-phen-yl)-2-(trityl-amino)-propano-ate.

作者信息

Chen Meimei, Lai Xinmei, Zhou Changen, Yang Xuemei

机构信息

College of Traditional Chinese Medicine, Fujian University of Traditional Chinese Medicine, Fuzhou, 350108 Fujian, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1412. doi: 10.1107/S1600536811017351. Epub 2011 May 14.

DOI:10.1107/S1600536811017351
PMID:21754794
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120518/
Abstract

The title compound, C(35)H(31)NO(3), was obtained by the reaction of (S)-benzyl 2-amino-3-(4-hy-droxy-phen-yl)propano-ate and (chloro-methane-tri-yl)tribenzene. The enanti-omer has been assigned by reference to an unchanging chiral centre in the synthetic procedure. In the crystal, mol-ecules are linked into chains running along the a axis by inter-molecular O-H⋯O hydrogen bonds.

摘要

标题化合物C(35)H(31)NO(3)是通过(S)-苄基2-氨基-3-(4-羟基苯基)丙酸酯与(氯甲烷三基)三苯反应制得的。通过参考合成过程中一个不变的手性中心确定了对映体。在晶体中，分子通过分子间O-H⋯O氢键连接成沿a轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44bc/3120518/4d3fd9a03275/e-67-o1412-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44bc/3120518/4d3fd9a03275/e-67-o1412-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44bc/3120518/4d3fd9a03275/e-67-o1412-fig1.jpg

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本文引用的文献

1
(S)-Benzyl 2-amino-3-(4-hydroxy-phen-yl)propanoate.（S）-2-氨基-3-（4-羟基苯基）丙酸苄酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 10;65(Pt 2):o270. doi: 10.1107/S1600536808044218.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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Synthesis of the side chain cross-linked tyrosine oligomers dityrosine, trityrosine, and pulcherosine.侧链交联酪氨酸低聚物二酪氨酸、三酪氨酸和美丽鼠尾草素的合成。
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