Wang Nuan-Sheng, Wang Yong-Tao, Guo Xiu-Kai, Li Tian-Duo
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1438. doi: 10.1107/S1600536811017934. Epub 2011 May 20.
The title compound, C(34)H(40)N(2)O(4)·2C(3)H(7)NO, was synthesized by the Mannich condensation of ethane-diamine, formaldehyde and p-cresol. In the crystal, the tetra-phenol mol-ecule is arranged around an inversion center. The mol-ecule and the dimethyl-formamide solvate are linked through an O-H⋯O hydrogen bond. An intra-molecular O-H⋯N hydrogen bond occurs in the tetra-phenol mol-ecule, which may influence the mol-ecular confomation. Futhermore, C-H⋯O and π-π stacking inter-actions [centroid-centroid distance = 3.7081 (14) Å] stabilize the crystal packing, building a three-dimensional network.
标题化合物C(34)H(40)N(2)O(4)·2C(3)H(7)NO是通过乙二胺、甲醛和对甲酚的曼尼希缩合反应合成的。在晶体中,四酚分子围绕一个反演中心排列。该分子与二甲基甲酰胺溶剂化物通过O-H⋯O氢键相连。在四酚分子中存在分子内O-H⋯N氢键,这可能会影响分子构象。此外,C-H⋯O和π-π堆积相互作用[质心-质心距离 = 3.7081 (14) Å]使晶体堆积稳定,构建了一个三维网络。