Fun Hoong-Kun, Quah Ching Kheng, Huang Chengmei, Yu Haitao
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1517-8. doi: 10.1107/S160053681101899X. Epub 2011 May 25.
In the isoquinoline ring system of the title mol-ecule, C(22)H(20)N(2)O(5), the N-heterocyclic ring is in a half-boat conformation. The least-squares plane of the dioxa-2-aza-spiro ring [maximum deviation = 0.076 (1) Å] and forms a dihedral angle of 14.54 (4)° with the phenyl ring. In the crystal, mol-ecules are linked via inter-molecular C-H⋯O hydrogen bonds into layers parallel to (100).
在标题分子C(22)H(20)N(2)O(5)的异喹啉环系统中,N-杂环呈半船式构象。二氧杂-2-氮杂螺环的最小二乘平面[最大偏差 = 0.076 (1) Å] 与苯环形成14.54 (4)°的二面角。在晶体中,分子通过分子间C-H⋯O氢键连接成平行于(100)的层。