Loh Wan-Sin, Fun Hoong-Kun, Sarveswari S, Vijayakumar V, Prasath R
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1521-2. doi: 10.1107/S1600536811019088. Epub 2011 May 25.
In the title compound, C(27)H(24)N(2)O·0.7H(2)O, the quinoline ring system is approximately planar, with a maximum deviation of 0.011 (1) Å, and forms dihedral angles of 74.70 (4) and 80.14 (4)° with the phenyl and benzene rings, respectively. In the crystal, the mol-ecules are linked to the water mol-ecules via inter-molecular O-H⋯N hydrogen bonds and further stabilized by C-H⋯π inter-actions involving the centroid of the benzene ring of the quinoline group. This benzene ring is observed to form a π-π inter-action with an adjacent pyridine ring [centroid-centroid distance = 3.7120 (6) Å].
在标题化合物C(27)H(24)N(2)O·0.7H(2)O中,喹啉环系近似平面,最大偏差为0.011 (1) Å,分别与苯环和苯基环形成74.70 (4)°和80.14 (4)°的二面角。在晶体中,分子通过分子间O-H⋯N氢键与水分子相连,并通过涉及喹啉基团苯环质心的C-H⋯π相互作用进一步稳定。观察到该苯环与相邻吡啶环形成π-π相互作用[质心-质心距离 = 3.7120 (6) Å]。