Schmitt Volker, Schollmeyer Dieter, Detert Heiner
University Mainz, Duesbergweg 10-14, 55099 Mainz, Germany.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1553. doi: 10.1107/S1600536811019714. Epub 2011 May 28.
In the title compound, C(44)H(48)N(6), the essentially planar mol-ecule [maximum deviation from the mean plane of the π system of 0.271 (3) Å] is located on a crystallographic centre of inversion. The almost planar (angle sums at N atoms = 357.6 and 357.1°) dimethyl-amino groups and short C-N bonds of the aniline groups [both 1.379 (4) Å] indicate strong electronic coupling between these groups and the central pyrazine ring.
在标题化合物C(44)H(48)N(6)中,基本呈平面状的分子[与π体系平均平面的最大偏差为0.271 (3) Å]位于一个晶体学反演中心上。几乎呈平面状的(N原子处的角度总和分别为357.6°和357.1°)二甲氨基以及苯胺基团的短C-N键[均为1.379 (4) Å]表明这些基团与中心吡嗪环之间存在强电子耦合。