Institute of Organic Chemistry, KIT-Campus South, Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany.
Chem Commun (Camb). 2011 Aug 28;47(32):9063-5. doi: 10.1039/c1cc12950c. Epub 2011 Jul 13.
A novel access to deuterated and D(3)CO-substituted arenes has been developed using immobilized triazenes as precursors. The linker system and the deuterating cleavage methodology could be shown to be compatible with various functional groups and are therefore suitable for the synthesis of derivatives only hardly available via comparable protocols.
一种新型的氘代和 D(3)CO 取代芳基的方法已经开发出来,使用固定化三氮烯作为前体。连接系统和氘代裂解方法被证明与各种官能团兼容,因此适合合成仅通过类似的方法难以获得的衍生物。