Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, 1 Nanyang Walk, Block 5 Level 3, Nanyang Technological University, Singapore 637371, Singapore.
Chem Commun (Camb). 2011 Aug 28;47(32):9066-8. doi: 10.1039/c1cc12926k. Epub 2011 Jul 14.
Indium-mediated allylation has been used in the site-selective functionalization of N-terminal aldehydes of peptides and proteins. This is the first demonstration of indium-mediated C-C bond formation in protein labelling studies under mild and environmentally friendly conditions.
铟介导的烯丙基化反应已被用于肽和蛋白质的 N 端醛基的选择性功能化。这是在温和、环保条件下进行的蛋白质标记研究中首次证明铟介导的 C-C 键形成。
