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Umpolung reactivity of indole through gold catalysis.

作者信息

Lu Biao, Luo Yingdong, Liu Lianzhu, Ye Longwu, Wang Yanzhao, Zhang Liming

机构信息

Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA, USA.

出版信息

Angew Chem Int Ed Engl. 2011 Aug 29;50(36):8358-62. doi: 10.1002/anie.201103014. Epub 2011 Jul 14.

DOI:10.1002/anie.201103014
PMID:21761530
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3465525/
Abstract
摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1645/3465525/b85fd85ea933/nihms394032f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1645/3465525/6fbb73ebc6a3/nihms394032f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1645/3465525/b85fd85ea933/nihms394032f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1645/3465525/6fbb73ebc6a3/nihms394032f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1645/3465525/b85fd85ea933/nihms394032f2.jpg

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本文引用的文献

1
Gold-catalyzed transformation of 2-alkynyl arylazides: efficient access to the valuable pseudoindoxyl and indolyl frameworks.
Angew Chem Int Ed Engl. 2011 Aug 1;50(32):7354-8. doi: 10.1002/anie.201102707. Epub 2011 Jun 24.
2
Update 1 of: Synthesis and functionalization of indoles through palladium-catalyzed reactions.《通过钯催化反应合成吲哚及其官能团化》更新1
Chem Rev. 2011 May 11;111(5):PR215-83. doi: 10.1021/cr100403z. Epub 2011 May 5.
3
A flexible and stereoselective synthesis of azetidin-3-ones through gold-catalyzed intermolecular oxidation of alkynes.通过金催化炔烃的分子间氧化反应，实现了氮杂环丁烷-3-酮的灵活和立体选择性合成。
Angew Chem Int Ed Engl. 2011 Mar 28;50(14):3236-9. doi: 10.1002/anie.201007624. Epub 2011 Mar 4.
4
Gold-catalyzed nitrene transfer to activated alkynes: formation of α,β-unsaturated amidines.金催化的氮宾转移到活化的炔烃：α,β-不饱和脒的形成。
Org Lett. 2011 Apr 1;13(7):1738-41. doi: 10.1021/ol2002607. Epub 2011 Feb 25.
5
Gold-catalyzed synthesis of benzil derivatives and α-keto imides via oxidation of alkynes.金催化炔烃氧化合成二苯甲酮衍生物和α-酮酰亚胺。
Org Lett. 2011 Mar 18;13(6):1556-9. doi: 10.1021/ol200270t. Epub 2011 Feb 18.
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Gold-catalyzed synthesis of 3-pyrrolidinones and nitrones from N-sulfonyl hydroxylamines via oxygen-transfer redox and 1,3-sulfonyl migration.通过氧转移氧化还原和1,3-磺酰基迁移，由N-磺酰基羟胺经金催化合成3-吡咯烷酮和硝酮。
Chemistry. 2011 Feb 7;17(6):1764-7. doi: 10.1002/chem.201002863. Epub 2011 Jan 5.
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