镧系元素锑的卤氧化物：从离散的纳米团簇到无机-有机杂化链和层。
Lanthanide antimony oxohalides: from discrete nanoclusters to inorganic-organic hybrid chains and layers.
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, PR China.
出版信息
Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8110-3. doi: 10.1002/anie.201103127. Epub 2011 Jul 14.
Structures à la carte: the combination of lone pairs and halide ions yields a praseodymium antimony oxohalide nanocluster Pr(4)Sb(12)O(18)Cl(17) with nearly perfect T(d) symmetry. Inorganic-organic hybrid compounds with 1D chain structure and 2D wave layer structure were assembled using dicarboxylic ligands with angular or linear geometry to interconnect the nanoclusters as secondary building units.
定制结构
孤对电子和卤素离子的组合生成具有近乎完美的 T(d)对称性的镨锑氧卤纳米团簇Pr(4)Sb(12)O(18)Cl(17)。使用具有角状或线状几何形状的二羧酸配体，将纳米团簇作为次级构筑单元连接起来，组装出具有 1D 链状结构和 2D 波浪层状结构的无机-有机杂化化合物。
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