一种具有高对映选择性的双功能螺型有机催化剂：在氮杂-Morita-Baylis-Hillman 反应中的应用。
A bifunctional spiro-type organocatalyst with high enantiocontrol: application to the aza-Morita-Baylis-Hillman reactions.
机构信息
The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka, Ibaraki-shi, Osaka 567-0047, Japan.
出版信息
Chem Commun (Camb). 2011 Aug 28;47(32):9227-9. doi: 10.1039/c1cc12784e. Epub 2011 Jul 18.
PMID:21769347
Abstract
A unique spiro-type Brønsted acid-Lewis base organocatalyst has been developed. The new bifunctional organocatalyst promoted aza-Morita-Baylis-Hillman reactions to yield adducts with up to 98% ee.
摘要
一种独特的螺型 Brønsted 酸-路易斯碱有机催化剂已被开发出来。新型双功能有机催化剂促进了氮杂-Morita-Baylis-Hillman 反应，以高达 98%的对映选择性得到加合物。
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