[Periodate oxidation of sucrose derivatives].
作者信息
Badel A, Descotes G, Mentech J
机构信息
Laboratoire de Chimie Organique II, U.R.A. du C.N.R.S. 463, Université Lyon I, Villeurbanne, France.
出版信息
Carbohydr Res. 1990 Sep 19;205:323-31. doi: 10.1016/0008-6215(90)80150-2.
PMID:2177378
Abstract
The periodate oxidation of some derivatives of sucrose at primary positions is generally selective for the D-glucopyranoside group. A cleavage at C-2-C3 or C-3-C-4 positions was observed for the 6,1',6'-tri-O-trityl and 6,1',6'-tri-O-(tert-butyldemethylsilyl) derivatives, respectively. The periodate oxidation was more complete for all other derivatives with a cleavage at C-2-C-3 and C-3-C-4.
摘要
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