State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, PR China.
Chem Commun (Camb). 2011 Sep 7;47(33):9441-3. doi: 10.1039/c1cc13314d. Epub 2011 Jul 21.
Monodisperse CuInS(2) nanocrystals are produced by injecting mixed metal-oleate precursors into hot organic solvents containing the dissolved sulphur sources. A better understanding of the formation mechanism of CuInS(2) has enabled us to tailor anisotropic shapes in the form of triangular-pyramid, circular cone, and bullet-like rods with tunable crystal phases by varying the synthetic conditions.
通过将混合金属配合物前驱体注入含有溶解的硫源的热有机溶剂中,制备出了单分散的 CuInS(2) 纳米晶体。对 CuInS(2) 形成机制的更好理解使我们能够通过改变合成条件,以三角形金字塔、圆形圆锥和子弹状棒的形式定制各向异性形状,并具有可调谐的晶体相。