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[广东云浮铊污染区水体中重金属分布及污染评价]

[Distribution of heavy metals in waters and pollution assessment in thallium contaminated area of Yunfu, Guangdong].

作者信息

Li Xiang-ping, Qi Jian-ying, Wang Chun-lin, Chen Yong-heng

机构信息

School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510004, China.

出版信息

Huan Jing Ke Xue. 2011 May;32(5):1321-8.

PMID:21780586
Abstract

Distribution of Thallium(T1), Cadmium( Cd), Chromium (Cr), Lead (Pb), Nickel (Ni), Arsenic (As), Copper (Cu), Zinc (Zn) in water and sediments of Yunfu pyrite mine area was studied. The environmental risk assessment was conducted systematically using Sediment Quality Guidelines (SQGs) and Hakanson potential ecological risk index. The results indicated that concentration range of Tl in stream water was 0.19-65.25 microg/L, which is higher than the environmental quality standards for surface water. Concentration ranges of Tl, Zn, As, Cd, Pb in sediments were 5.89-63.0 mg/kg, 1215-5754 mg/kg, 208.4-1327 mg/kg, 4.20-17.5 mg/kg, 282-13,770 mg/kg. According to Sediments Quality Guidelines, sediments was moderately to severe level of pollution since concentrations of Tl, Cd, Cr, Pb, Ni, As, Cu, Zn were much higher than LEL (lowest effect level) values, and the concentrations of Pb, As, Zn were higher than SEL (severe effect level) values, the others were partly higher than SEL values, which may result in severe negative biota effects in the watersheds. Compared to soil background values of Guangdong province, the metals in stream sediment showed strong to severe strong ecological risk, and the ecological risk of heavy metals in the descending order of Tl, Cd, As, Pb, Cr, Ni, Zn and Cu. Besides, the sediments were severe contained by toxic element thallium and cadmium. Besides, the mainly ecological risk of heavy metal is thallium. More emphasis should be placed on thallium and cadmium control and disposal in

摘要

研究了云浮硫铁矿矿区水体和沉积物中铊(Tl)、镉(Cd)、铬(Cr)、铅(Pb)、镍(Ni)、砷(As)、铜(Cu)、锌(Zn)的分布情况。采用沉积物质量基准(SQGs)和哈坎森潜在生态风险指数对环境风险进行了系统评估。结果表明,溪水中铊的浓度范围为0.19 - 65.25微克/升,高于地表水环境质量标准。沉积物中铊、锌、砷、镉、铅的浓度范围分别为5.89 - 63.0毫克/千克、1215 - 5754毫克/千克、208.4 - 1327毫克/千克、4.20 - 17.5毫克/千克、282 - 13770毫克/千克。根据沉积物质量基准,沉积物处于中度至重度污染水平,因为铊、镉、铬、铅、镍、砷、铜、锌的浓度远高于最低效应水平(LEL)值,铅、砷、锌的浓度高于严重效应水平(SEL)值,其他部分高于SEL值,这可能在流域内对生物群产生严重的负面影响。与广东省土壤背景值相比,溪流沉积物中的金属呈现出强至极强的生态风险,重金属生态风险由高到低依次为铊、镉、砷、铅、铬、镍、锌和铜。此外,沉积物中含有严重的有毒元素铊和镉。此外,重金属的主要生态风险是铊。在……中应更加重视铊和镉的控制与处置

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