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非平衡气流中辐射与振动-平动弛豫及解离耦合的状态对状态建模。

State-to-state modeling of radiation coupled to vibration-translation relaxation and dissociation in nonequilibrium gas flows.

作者信息

Aliat A, Vedula P, Josyula E

机构信息

School of Aerospace and Mechanical Engineering, University of Oklahoma, Norman, Oklahoma 73019, USA.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2011 Jun;83(6 Pt 2):067302. doi: 10.1103/PhysRevE.83.067302. Epub 2011 Jun 16.

DOI:10.1103/PhysRevE.83.067302
PMID:21797519
Abstract

A radiation model is developed to obtain evolution of band intensities according to the state-to-state (STS) approach by considering vibration-translation and vibration-electronic jumps and dissociation. Investigation of the behavior of a nonequilibrium N(2) gas flow behind a shock shows that the radiation intensity remains weak and the flow is far from radiative equilibrium. Similar intensities are predicted by pure STS and hybrid approaches based on existing radiation models. However, the coupling between physicochemical and radiative processes increases with radiation intensity.

摘要

通过考虑振动-平动、振动-电子跃迁和解离,开发了一种辐射模型,以根据态-态(STS)方法获得谱带强度的演变。对激波后非平衡N₂气流行为的研究表明,辐射强度仍然较弱,且气流远未达到辐射平衡。基于现有辐射模型的纯STS方法和混合方法预测出了相似的强度。然而,物理化学过程与辐射过程之间的耦合随着辐射强度的增加而增强。

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