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α-Al2O3 添加剂对粉煤灰基地聚物产品的微观结构、力学性能和甲醛吸附性能的影响。

The influence of α-Al2O3 addition on microstructure, mechanical and formaldehyde adsorption properties of fly ash-based geopolymer products.

机构信息

School of Chemical & Environmental Engineering, China University of Mining and Technology, Beijing 100083, PR China.

出版信息

J Hazard Mater. 2011 Oct 15;193:90-4. doi: 10.1016/j.jhazmat.2011.07.029. Epub 2011 Jul 18.

Abstract

Fly ash-based geopolymer with α-Al(2)O(3) addition were synthesized and used to remove formaldehyde from indoor air. The microstructure, mechanical and formaldehyde adsorption properties of the geopolymer products obtained were investigated. The results showed that α-Al(2)O(3) addition with appropriate amount (such as 5 wt%) increased the geopolymerization extent, resulting in the increase of surface area and compressive strength. In addition, the improvement of structural ordering level for geopolymer sample with 5 wt% α-Al(2)O(3) addition was found through FTIR analysis. By contrast, excessive addition (such as 10 wt%) had the opposite effect. The test of formaldehyde adsorption capacity confirmed that fly ash-based geopolymer product exhibited much better property of adsorbing indoor formaldehyde physically and chemically than fly ash itself. The surface area was an important but not unique factor influencing the adsorption capacity of geopolymers.

摘要

添加α-Al(2)O(3)的粉煤灰基地聚物的合成及其用于去除室内空气中的甲醛。研究了所得到的地聚物产物的微观结构、力学性能和甲醛吸附性能。结果表明,适量(如 5wt%)添加α-Al(2)O(3)增加了聚合程度,从而增加了表面积和抗压强度。此外,通过 FTIR 分析发现,添加 5wt%α-Al(2)O(3 的地聚物样品的结构有序度水平提高。相比之下,过量添加(如 10wt%)则产生相反的效果。甲醛吸附容量的测试证实,与粉煤灰本身相比,基于粉煤灰的地聚物产品在物理和化学吸附室内甲醛方面表现出更好的性能。表面积是影响地聚物吸附能力的一个重要但不是唯一的因素。

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