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Overview of Carbanion Dynamics and Electrophilic Substitutions in Chiral Organolithium Compounds.

作者信息

Gawley Robert E

机构信息

Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas, 72701 USA.

出版信息

Top Stereochem. 2010 Jan 1;26:93-133. doi: 10.1002/9783906390628.ch3.

DOI:10.1002/9783906390628.ch3
PMID:21804654
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3145419/
Abstract
摘要

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本文引用的文献

1
Solid-State Structural Investigation of an Organolithium (-)-Sparteine Complex: η -N-Boc-N-(p-methoxyphenyl)-3-phenylallyllithium⋅(-)-Sparteine.一种有机锂(-)-司巴丁配合物的固态结构研究:η -N-叔丁氧羰基-N-(对甲氧基苯基)-3-苯基烯丙基锂⋅(-)-司巴丁
Angew Chem Int Ed Engl. 1998 Oct 2;37(18):2522-2524. doi: 10.1002/(SICI)1521-3773(19981002)37:18<2522::AID-ANIE2522>3.0.CO;2-T.
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Perspectives on computational organic chemistry.计算有机化学展望
J Org Chem. 2009 Jun 19;74(12):4433-46. doi: 10.1021/jo900497s.
3
Enantiomerization dynamics and a catalytic dynamic resolution of N-trimethylallyl-2-lithiopyrrolidine.N-三甲基烯丙基-2-锂代吡咯烷的对映异构化动力学及催化动态拆分
J Am Chem Soc. 2009 May 27;131(20):6908-9. doi: 10.1021/ja900755a.
4
Dynamic thermodynamic resolution: advantage by separation of equilibration and resolution.动态热力学拆分:通过平衡与拆分的分离实现优势。
Acc Chem Res. 2009 Feb 17;42(2):224-34. doi: 10.1021/ar8000662.
5
The barrier to enantiomerization of N-Boc-2-lithiopyrrolidine: the effect of chiral and achiral diamines.N-叔丁氧羰基-2-锂代吡咯烷对映异构化的障碍:手性和非手性二胺的影响。
Chem Commun (Camb). 2008 Jan 7(1):97-8. doi: 10.1039/b714302h.
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Chiral tertiary diamines in asymmetric synthesis.不对称合成中的手性叔二胺
Chem Rev. 2008 Jan;108(1):140-205. doi: 10.1021/cr040107v. Epub 2007 Dec 15.
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Configurational and conformational effects on tin-lithium exchange in alpha-aminoorganostannanes by rapid-injection NMR.通过快速注入核磁共振研究α-氨基有机锡烷中锡-锂交换的构型和构象效应。
J Am Chem Soc. 2007 Apr 11;129(14):4126-7. doi: 10.1021/ja0692377. Epub 2007 Mar 16.
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Diastereoselectivity of polar and radical couplings in electrophilic substitutions of rigid 2-lithio-N-methylpyrrolidines.
Org Biomol Chem. 2006 Dec 7;4(23):4285-91. doi: 10.1039/b608013h. Epub 2006 Oct 20.
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Dynamic thermodynamic and dynamic kinetic resolution of 2-lithiopyrrolidines.2-锂代吡咯烷的动态热力学和动态动力学拆分
J Am Chem Soc. 2006 Aug 23;128(33):10943-51. doi: 10.1021/ja061963m.
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Highly diastereoselective formation and reactions of a non-mesomerically stabilized, lithiated alpha-thiocarbanion.
Chem Commun (Camb). 2006 Aug 7(29):3101-3. doi: 10.1039/b604029b. Epub 2006 Jun 14.