Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China.
Colloids Surf B Biointerfaces. 2011 Nov 1;88(1):396-401. doi: 10.1016/j.colsurfb.2011.07.020. Epub 2011 Jul 18.
The hydroxide of meso-tetraphenylporphyrin derivatives functionalized carbon nanotubes (CNTs) was fabricated in our research to explore the interaction between porphyrin and explosive. It was turned out that in the formation of grid porphyrin film, carbon nanotubes as a cruciul base materials promoted the electron transfer rate. Most of important, the results also showed that the electrochemical response was enhanced through increasing the number of -OH substitution in porphyrin. Such information provides the platform for a practical strategy for rational design of the sensor of explosives.
在我们的研究中，制备了功能化碳纳米管（CNTs）的间四苯基卟啉衍生物的氢氧化物，以探索卟啉与爆炸物之间的相互作用。结果表明，在网格卟啉膜的形成过程中，碳纳米管作为关键的基底材料，促进了电子转移速率。更重要的是，结果还表明，通过增加卟啉中的-OH 取代数量，可以增强电化学响应。这些信息为合理设计爆炸物传感器的实用策略提供了平台。
