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准一维导体A(0.30)MoO(3)(A = K、Rb)和Rb(0.30)(Mo(1 - x)V(x))O(3)在50K附近的超声特性

Ultrasonic properties near 50 K of the quasi-one-dimensional conductors A(0.30)MoO(3) (A = K, Rb) and Rb(0.30)(Mo(1-x)V(x))O(3).

作者信息

Saint-Paul M, Dumas J, Marcus J

机构信息

Institut Néel, CNRS/UJF, BP 166, F-38042 Grenoble Cedex 9, France.

出版信息

J Phys Condens Matter. 2009 May 27;21(21):215603. doi: 10.1088/0953-8984/21/21/215603. Epub 2009 Apr 24.

Abstract

The charge density wave (CDW) nonlinear conductivity of the blue bronzes A(0.30)MoO(3) (A = K, Rb) shows two different regimes depending on the temperature: a strongly damped CDW motion above ∼50 K and a CDW motion with almost no damping below ∼50 K. In a search for an elastic signature of this CDW behaviour, we performed ultrasonic measurements on A(0.30)MoO(3) single crystals in the temperature range 4-300 K. In Rb(0.30)MoO(3), at T∼50 K, upon cooling, a large increase of the sound velocity for the longitudinal mode measured along the [Formula: see text], [102] and b directions is observed. The ultrasonic attenuation coefficient shows an increase down to 50 K followed by a plateau. Similar results are found in K(0.30)MoO(3). In V-doped samples, Rb(0.30)(Mo(1-x)V(x))O(3) (x = 0.4%) the anomaly broadens and is shifted towards higher temperatures. The results are discussed in relation to the changes in the CDW rigidity, disorder and dielectric response. A scenario based on a glass transition for the CDW superstructure is proposed.

摘要

蓝色青铜A(0.30)MoO(3)(A = K、Rb)的电荷密度波(CDW)非线性电导率根据温度表现出两种不同状态:在约50K以上为强阻尼CDW运动,在约50K以下为几乎无阻尼的CDW运动。为了寻找这种CDW行为的弹性特征,我们在4 - 300K温度范围内对A(0.30)MoO(3)单晶进行了超声测量。在Rb(0.30)MoO(3)中,在T约为50K时,冷却过程中,观察到沿[公式:见正文]、[102]和b方向测量的纵向模式声速大幅增加。超声衰减系数在降至50K之前增加,之后趋于平稳。在K(0.30)MoO(3)中也发现了类似结果。在V掺杂样品Rb(0.30)(Mo(1 - x)V(x))O(3)(x = 0.4%)中,异常变宽并向更高温度移动。结合CDW刚度、无序度和介电响应的变化对结果进行了讨论。提出了一种基于CDW超结构玻璃化转变的设想。

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