基于四核[W（Mo）OS3Cu3]+次级构筑单元的（10,3）-型 MOFs 的合理合成。
The rational synthesis of (10,3)-type MOFs based on tetranuclear [W(Mo)OS3Cu3]+ secondary building units.
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P.R. China.
出版信息
Chem Commun (Camb). 2011 Sep 28;47(36):10049-51. doi: 10.1039/c1cc12691a. Epub 2011 Aug 8.
PMID:21826299
Abstract
The self-assembly reaction of the preformed clusters with two extended linear and trigonal rigid ligands as organic linkers afforded two 2D and 3D Mo(W)/Cu/S-based cluster polymers. They show unprecedented structure types in Mo(W)/S/Cu chemistry and exhibit strong third-order nonlinear optical properties.
摘要
预形成的簇与两个扩展的线性和三角刚性配体作为有机连接体的自组装反应提供了两种 2D 和 3D 的 Mo(W)/Cu/S 基簇聚合物。它们在 Mo(W)/S/Cu 化学中表现出前所未有的结构类型，并具有很强的三阶非线性光学性质。
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