五氟苯基卤代卡宾。
Pentafluorophenylhalocarbenes.
机构信息
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA.
出版信息
Org Lett. 2011 Sep 2;13(17):4752-4. doi: 10.1021/ol2019532. Epub 2011 Aug 9.
PMID:21827182
Abstract
Pentafluorophenylchlorocarbene and pentafluorophenylfluorocarbene are highly reactive species and effective carriers of fluorine labels via addition to alkenes and insertion into C-H bonds.
摘要
五氟苯基氯碳烯和五氟苯基氟碳烯是高反应性物质，通过与烯烃加成和插入 C-H 键，可有效携带氟标记。
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