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基于微乳液法合成多孔铁酸锌纳米棒及其在室温乙醇传感器中的应用

Microemulsion-based synthesis of porous zinc ferrite nanorods and its application in a room-temperature ethanol sensor.

作者信息

Zhu Hongliang, Gu Xiaoyun, Zuo Diantai, Wang Zhengkai, Wang Naiyan, Yao Kuihong

出版信息

Nanotechnology. 2008 Oct 8;19(40):405503. doi: 10.1088/0957-4484/19/40/405503. Epub 2008 Aug 20.

Abstract

Porous zinc ferrite (ZnFe(2)O(4)) nanorods with a diameter of around 50 nm and a length of several micrometers have been synthesized by a microemulsion-based method in combination with calcination at 500 °C. The morphology and structure of the ZnFe(2)O(4) nanorods and its precursor (ZnFe(2)(C(2)O(4))(3) nanorods) were systematically characterized by x-ray powder diffraction, transmission electron microscopy, field emission scanning electron microscopy and high-resolution transmission electron microscopy. The formation mechanism for the porous ZnFe(2)O(4) nanorods is also discussed. Moreover, the porous ZnFe(2)O(4) nanorods were applied in a room-temperature ethanol sensor and exhibited much better sensing performance than ZnFe(2)O(4) nanoparticles.

摘要

采用基于微乳液的方法并结合在500°C下煅烧,合成了直径约50纳米、长度为几微米的多孔铁酸锌(ZnFe₂O₄)纳米棒。通过X射线粉末衍射、透射电子显微镜、场发射扫描电子显微镜和高分辨率透射电子显微镜对ZnFe₂O₄纳米棒及其前驱体(ZnFe₂(C₂O₄)₃纳米棒)的形貌和结构进行了系统表征。还讨论了多孔ZnFe₂O₄纳米棒的形成机理。此外,将多孔ZnFe₂O₄纳米棒应用于室温乙醇传感器,其传感性能比ZnFe₂O₄纳米颗粒好得多。

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