Cao H B, Gukasov A, Mirebeau I, Bonville P
CEA, Centre de Saclay, Laboratoire Léon Brillouin, F-91191 Gif-sur-Yvette, France.
J Phys Condens Matter. 2009 Dec 9;21(49):492202. doi: 10.1088/0953-8984/21/49/492202. Epub 2009 Nov 19.
The local Yb(3+) magnetic susceptibility tensor was recently measured in the frustrated pyrochlore compound Yb(2)Ti(2)O(7) by means of in-field polarized neutron scattering in a single crystal. A very anisotropic effective exchange tensor was derived for the Yb(3+) ion. Using this result, we reinterpret here the data for the powder susceptibility in Yb(2)Ti(2)O(7). We show that, in the case of a well-isolated Kramers doublet with anisotropic g and exchange tensors, the inverse susceptibility for a powder sample does not strictly obey a Curie-Weiss law at low temperature. We discuss the consequences regarding the paramagnetic Curie temperature, usually taken as a measure of the exchange/dipolar interaction, and the exotic 'slow fluctuation' ground state of Yb(2)Ti(2)O(7).
最近,通过对单晶进行场极化中子散射,测量了受挫的烧绿石化合物Yb₂Ti₂O₇中的局部Yb(3+)磁化率张量。推导出了Yb(3+)离子的一个非常各向异性的有效交换张量。利用这一结果,我们在此重新解释Yb₂Ti₂O₇中粉末磁化率的数据。我们表明,在具有各向异性g和交换张量的良好隔离的克莱默斯双重态的情况下,粉末样品的逆磁化率在低温下并不严格遵循居里-外斯定律。我们讨论了关于顺磁居里温度(通常被视为交换/偶极相互作用的量度)以及Yb₂Ti₂O₇奇异的“慢涨落”基态的相关后果。