Andraka B, Rotundu C R, Takano Y, Tsujii H
Department of Physics, University of Florida, PO Box 118440, Gainesville, FL 32611-8440, USA.
J Phys Condens Matter. 2009 Dec 2;21(49):495601. doi: 10.1088/0953-8984/21/49/495601. Epub 2009 Nov 12.
Strongly diluted Ce(x)La(1-x)Al(3) alloys have been studied by the low temperature specific heat in order to elucidate the mechanism that determines their ground state. The results for alloys with Ce concentrations of 0.0005≤x≤0.1 are fairly consistent with a S = 1/2 Kondo behavior. However, the single-ion scaling is observed only below x = 0.01. The true single-ion Kondo temperature is small, 0.2 K, approximately equal to that for dilute CeAl(2). It is about 20 times smaller than that for CeAl(3), indicating the coherent nature of CeAl(3). The single-ion contribution to thermodynamic properties of CeAl(3) is negligible even at temperatures as high as 5 K.
为了阐明决定其基态的机制,我们通过低温比热研究了高度稀释的Ce(x)La(1 - x)Al(3)合金。Ce浓度为0.0005≤x≤0.1的合金的结果与S = 1/2近藤行为相当一致。然而,单离子标度仅在x < 0.01时才被观察到。真正的单离子近藤温度很小,为0.2 K,大约等于稀CeAl(2)的近藤温度。它比CeAl(3)的近藤温度小约20倍,这表明CeAl(3)的相干性质。即使在高达5 K的温度下,CeAl(3)的单离子对热力学性质的贡献也可以忽略不计。