1-氯甲基-1,4-重氮双环[2.2.2]辛烷四氯化铜（II）
1-Chloro-methyl-1,4-diazo-niabicyclo[2.2.2]octane tetra-chloridocuprate(II).
作者信息
Rong Tao
机构信息
Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m889. doi: 10.1107/S1600536811020782. Epub 2011 Jun 11.
Abstract
In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter-molecular N-H⋯Cl hydrogen bond is observed between the organic dication and the tetrahedral CuCl(4) anion. The organic dication is distorted, as indicated by the N-C-C-N torsion angles, which range from 16.76 (4) to 19.54 (3)°.
摘要
在标题化合物（C₇H₁₅ClN₂）[CuCl₄]的晶体结构中，在有机二价阳离子与四面体[CuCl₄]²⁻阴离子之间观察到一个弱的分子间N - H⋯Cl氢键。如N - C - C - N扭转角所示，有机二价阳离子发生了扭曲，扭转角范围为16.76（4）至19.54（3）°。
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