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链状聚[[[水合-(甲酸根-κO)(1,10-菲咯啉-κN,N')锰(II)]-μ-甲酸根-κO:O']一水合物]

catena-Poly[[[aqua-(formato-κO)(1,10-phenanthroline-κN,N')manganese(II)]-μ-formato-κO:O'] monohydrate].

作者信息

Xu Wei

机构信息

Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo 315211, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m893. doi: 10.1107/S1600536811020575. Epub 2011 Jun 11.

DOI:10.1107/S1600536811020575
PMID:21836883
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3151819/
Abstract

The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex Mn(HCOO)(2)(phen)(H(2)O) (phen is 1,10-phenanthroline) with solvent water mol-ecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extended into a three-dimensional network via O-H⋯O hydrogen-bonding inter-actions and inter-chain π-π stacking inter-actions, with a centroid-centroid distance of 3.679 (4) Å.

摘要

标题化合物{[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n)由配合物Mn(HCOO)(2)(phen)(H(2)O)（phen为1,10-菲咯啉）的聚合物链和溶剂水分子组成。这些链包含由甲酸根阴离子桥连的六配位Mn(II)离子。它们通过O-H⋯O氢键相互作用和链间π-π堆积相互作用进一步扩展成三维网络，质心间距为3.679 (4) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8df2/3151819/94d0e1fd5112/e-67-0m893-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8df2/3151819/0d917344e5f9/e-67-0m893-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8df2/3151819/0c3ab3899679/e-67-0m893-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8df2/3151819/94d0e1fd5112/e-67-0m893-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8df2/3151819/0d917344e5f9/e-67-0m893-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8df2/3151819/0c3ab3899679/e-67-0m893-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8df2/3151819/94d0e1fd5112/e-67-0m893-fig3.jpg

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本文引用的文献

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Metal-organic perovskites: synthesis, structures, and magnetic properties of [C(NH2)3][M(II)(HCOO)3] (M = Mn, Fe, Co, Ni, Cu, and Zn; C(NH2)3 = guanidinium).金属有机钙钛矿：[C(NH2)3][M(II)(HCOO)3]（M = Mn、Fe、Co、Ni、Cu 和 Zn；C(NH2)3 = 胍基）的合成、结构和磁性。
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Metal-organic frameworks: opportunities for catalysis.金属有机框架：催化领域的机遇
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Crystal structure and magnetic properties of a new chiral manganese(II) three-dimensional framework: Na(3)[Mn(3)(HCOO)(9)].
一种新型手性锰（II）三维骨架：Na(3)[Mn(3)(HCOO)(9)]的晶体结构与磁性
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Intensely colored mixed-valence iron(II) iron(III) formate analogue of Prussian Blue exhibits néel N-type ferrimagnetism.普鲁士蓝的强色混合价态甲酸铁（II）铁（III）类似物表现出尼尔N型亚铁磁性。
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