链状聚[[[水合-(甲酸根-κO)(1,10-菲咯啉-κN,N')锰(II)]-μ-甲酸根-κO:O']一水合物]
catena-Poly[[[aqua-(formato-κO)(1,10-phenanthroline-κN,N')manganese(II)]-μ-formato-κO:O'] monohydrate].
作者信息
Xu Wei
机构信息
Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo 315211, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m893. doi: 10.1107/S1600536811020575. Epub 2011 Jun 11.
The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex Mn(HCOO)(2)(phen)(H(2)O) (phen is 1,10-phenanthroline) with solvent water mol-ecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extended into a three-dimensional network via O-H⋯O hydrogen-bonding inter-actions and inter-chain π-π stacking inter-actions, with a centroid-centroid distance of 3.679 (4) Å.
标题化合物{[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n)由配合物Mn(HCOO)(2)(phen)(H(2)O)（phen为1,10-菲咯啉）的聚合物链和溶剂水分子组成。这些链包含由甲酸根阴离子桥连的六配位Mn(II)离子。它们通过O-H⋯O氢键相互作用和链间π-π堆积相互作用进一步扩展成三维网络，质心间距为3.679 (4) Å。
Zotero 插件