Gowda B Thimme, Foro Sabine, Shakuntala K
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m914. doi: 10.1107/S1600536811021891. Epub 2011 Jun 11.
In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(-)·1.5H(2)O, one water mol-ecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzene-sulfonamide anions. The S-N distance of 1.582 (2) Å is consistent with an S-N double bond. In the structure, the sulfonyl-O and the water-O atoms bridge the K(+) cations in a bidentate fashion. The crystal structure comprises sheets in the ac plane which are further stabilized by inter-molecular O-H⋯Cl and O-H⋯N hydrogen bonds.
在标题化合物K⁺·C₆H₄Cl₂NO₂S⁻·1.5H₂O中,一个水分子具有晶体学上的二重对称性。K⁺离子由来自水分子的三个O原子和N - 氯 - 2 - 氯苯磺酰胺阴离子的四个磺酰基O原子七配位。S - N键长为1.582(2) Å,与S - N双键相符。在结构中,磺酰基 - O原子和水分子的O原子以双齿方式桥连K⁺阳离子。晶体结构在ac平面上形成片层,通过分子间的O - H⋯Cl和O - H⋯N氢键进一步稳定。