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{4,4'-Dichloro-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanyl-ylidene)]diphenolato-κO,N,N',O'}nickel(II).

作者信息

Kargar Hadi, Kia Reza, Pahlavani Elham, Tahir Muhammad Nawaz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m941. doi: 10.1107/S1600536811022732. Epub 2011 Jun 18.

Abstract

In the title compound, [Ni(C(19)H(18)Cl(2)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the crystal, pairs of inter-molecular C-H⋯O hydrogen bonds link neighboring mol-ecules into a chain along the a axis. The crystal structure is further stabilized by π-π inter-actions [centroid-centroid distance = 3.883 (2) Å].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3694/3151962/2c6399b6642f/e-67-0m941-fig1.jpg

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