{4,4'-二溴-2,2'-[2,2-二甲基丙烷-1,3-二亚基双(腈基亚甲基)]二酚根合-κO,N,N',O'}镍(II)
{4,4'-Dibromo-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato-κO,N,N',O'}nickel(II).
作者信息
Rayati Saeed, Ghaemi Akbar, Notash Behrouz
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m448. doi: 10.1107/S1600536811009056. Epub 2011 Mar 15.
Abstract
In the title compound, [Ni(C(19)H(18)Br(2)N(2)O(2))], the Ni(II) ion, lying on a twofold rotation axis, is coordinated by two N atoms and two O atoms from the Schiff base ligand in a distorted square-planar geometry. Weak inter-molecular C-H⋯O hydrogen bonds stabilize the crystal structure.
摘要
在标题化合物[Ni(C₁₉H₁₈Br₂N₂O₂)]中，位于二重旋转轴上的Ni(II)离子由席夫碱配体的两个N原子和两个O原子以扭曲的平面正方形几何构型配位。分子间弱的C—H⋯O氢键稳定了晶体结构。
Zotero 插件