Akhazzane Mohamed, Zouihri Hafid, Daoudi Maria, Kerbal Abdelali, Al Houari Ghali
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1828. doi: 10.1107/S1600536811021969. Epub 2011 Jun 25.
In the title compound C(22)H(24)O(2), the exocyclic C=C double bond is in an E configuration and the tert-butyl group is in an axial position on the cyclo-hexa-none ring. The cyclo-hexa-none ring in the dihydro-naphthalene fused-ring system adopts a half-chair conformation in both independent two mol-ecules in the asymetric unit. The benzene ring system is oriented angles of 43.97 (12) and 39.24 (12)° with respect to the naphthyl ring system in the two independent mol-ecules. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds and C-H⋯π inter-actions.
在标题化合物C₂₂H₂₄O₂中,环外C=C双键呈E构型,叔丁基位于环己酮环上的轴向位置。二氢萘稠环体系中的环己酮环在不对称单元中的两个独立分子中均采用半椅构象。在两个独立分子中,苯环体系相对于萘环体系的取向角度分别为43.97 (12)°和39.24 (12)°。在晶体中,分子通过C—H⋯O氢键和C—H⋯π相互作用相连。