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电化学生成的纳米结构银表面的化学行为。

Chemical behavior of electrochemically generated nanostructured silver surfaces.

机构信息

Department of Physical and Environmental Sciences, University of Toronto at Scarborough, 1265 Military Trail, Toronto, Ontario, M1C 1A4 Canada.

出版信息

Langmuir. 2011 Oct 4;27(19):12098-105. doi: 10.1021/la2015379. Epub 2011 Sep 9.

DOI:10.1021/la2015379
PMID:21866894
Abstract

A simple electrochemical method has been proposed for the preparation of silver nanoparticles that can be used for the detection of cyanide. Both the electrochemical behavior and morphology of the Ag nanoparticles have been characterized in the presence of KCN or diethyl cyanophosphonate (DECP) as well as in alkaline media. These were investigated by cyclic voltammetry and scanning electron microscopy (SEM). DECP is a simulant of the chemical warfare agent tabun.

摘要

一种简单的电化学方法被提出用于制备可用于检测氰化物的银纳米粒子。在存在 KCN 或二乙基氰膦酸酯(DECP)以及碱性介质的情况下,对 Ag 纳米粒子的电化学行为和形态进行了表征。这些通过循环伏安法和扫描电子显微镜(SEM)进行了研究。DECP 是化学战剂沙林的模拟物。

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