三配位 N-杂环卡宾铁(II)双(三甲基硅基)酰胺加合物的结构和键合。
Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(II) bis(trimethylsilyl)amide.
机构信息
School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK.
出版信息
Chem Commun (Camb). 2011 Oct 14;47(38):10623-5. doi: 10.1039/c1cc14576b. Epub 2011 Sep 1.
PMID:21881649
Abstract
The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC complexes [(NHC)Fe{N(SiMe(3))(2)}(2)] (NHC = IPr, 2; NHC = IMes, 3) are reported.
摘要
报道了三配位铁(II)NHC 配合物[(NHC)Fe{N(SiMe(3))(2)}(2)]（NHC = IPr，2；NHC = IMes，3）的分子结构、化学成键和磁化学性质。
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