Department of Chemical Engineering, The Petroleum Institute, P. O. Box 2533, Abu Dhabi, United Arab Emirates.
Arch Environ Contam Toxicol. 2012 Apr;62(3):361-8. doi: 10.1007/s00244-011-9706-7. Epub 2011 Sep 3.
The distribution of natural nuclide gamma-ray activities and their respective annual effective dose rates, produced by potassium-40 (⁴⁰K), uranium-238 (²³⁸U), thorium-232 (²³²Th), and radium-226 (²²⁶Ra), were determined for 14 oilfield scale samples from the Middle East. Accumulated radioactive materials concentrate in tubing and surface equipment, and workers at equipment-cleaning facilities and naturally occurring radioactive materials (NORMs) disposal facilities are the population most at risk for exposure to NORM radiation. Gamma-spectra analysis indicated that photo-gamma lines represent the parents of 10 radioactive nuclides: ²³⁴Th, plutonium-239, actinium-228, ²²⁶Ra, lead-212 (²¹²Pb), ²¹⁴Pb, thallium-238 (²⁰⁸Tl), bismuth-212 (²¹²Bi), ²¹⁴Bi, and ⁴⁰K. These nuclides represent the daughters of the natural radioactive series ²³⁸U and ²³²Th with ⁴⁰K as well. The mean activity concentration of ²³⁸U, ²³²Th, and ⁴⁰K were found to be 25.8 ± 11.6, 18.3 ± 8.1, and 4487.2 ± 2.5% Bq kg⁻¹ (average values for 14 samples), respectively. The annual effective dose rates and the absorbed doses in air, both indoor and outdoor, for the samples were obtained as well. The results can be used to assess the respective hazard on workers in the field and represent a basis for revisiting current engineering practices.
从中东地区采集了 14 个油田规模的样品,测定了钾-40(⁴⁰K)、铀-238(²³⁸U)、钍-232(²³²Th)和镭-226(²²⁶Ra)天然放射性核素γ射线活度及其各自的年有效剂量率。放射性物质在油管和地面设备中积累,在设备清洗设施和天然放射性物质(NORMs)处理设施工作的人员最容易受到 NORM 辐射的暴露。γ能谱分析表明,光γ谱线代表 10 种放射性核素的母体:²³⁴Th、钚-239、锕-228、²²⁶Ra、铅-212(²¹²Pb)、²¹⁴Pb、铊-238(²⁰⁸Tl)、铋-212(²¹²Bi)、²¹⁴Bi 和 ⁴⁰K。这些核素也是天然放射性系列 ²³⁸U 和 ²³²Th 的子体,同时也有 ⁴⁰K。发现 ²³⁸U、²³²Th 和 ⁴⁰K 的平均活度浓度分别为 25.8 ± 11.6、18.3 ± 8.1 和 4487.2 ± 2.5%Bq kg⁻¹(14 个样品的平均值)。还获得了样品的年有效剂量率以及室内和室外空气中的吸收剂量。这些结果可用于评估现场工人的风险,也为重新审视当前工程实践提供了依据。